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Pradeep Pradhan 21Pradeep Pradhan 21 

Create LWC component to add multiple contact related account. Add this component on account detail page. To achieve this use dynamic table. So, you can add/remove rows dynamically.

Suraj Tripathi 47Suraj Tripathi 47
Hi Pradeep Pradhan 21

Greetings!

The community cannot provide full code but If you are stuck somewhere we will help you so first can you provide us what you tried already so we can help you. but for your reference, I provide you a link that may help you with your scenario.
Link:
https://developer.salesforce.com/forums/?id=9062I000000XsGbQAK

if you find your solution mark this as the best answer.

Thank you!

Regards 
Suraj Tripathi.